Disposal and Decontamination of Pesticides by Maurice V. Kennedy
By Maurice V. Kennedy
content material: Conquering the monster : the photochemical destruction of chlorodioxins / D.G. Crosby --
techniques to decontamination or disposal of insecticides : photodecomposition / Jack R. Plimmer --
Catalytic hydrodechlorination of polychlorinated hydrocarbons / Wilmer L. Kranich, Rene B. Lapierre, Laszlo Guczi, and Alvin H. Weiss --
Photodegradation of halogenated xanthene dyes / James R. Heitz and W.W. Wilson --
detoxing of insecticides and unsafe wastes via the microwave plasma approach / Lionel J. Bailin, Barry L. Hertzler, and Donald A. Oberacker --
cutting-edge file on pesticide disposal learn / Ralph R. Wilkinson, Edward W. Lawless, Alfred F. Meiners, Thomas L. Ferguson, Gary L. Kelso, and Fred C. Hopkins --
Thermal degradation of chosen fungicides and pesticides / Maurice V. Kennedy, Miles E. Holloman, and Fay Y. Hutto --
constructing know-how for detoxing of insecticides and different dangerous fabrics / Charles J. Rogers and Robert Allen --
Pyrolysis and disposal of mirex residues / Bobby R. Layton and Earl G. Alley --
Destruction of insecticides and pesticide packing containers through molten salt combustion / S.J. Yosim, K.M. Barclay, and L.F. Grantham --
Binding and liberate of insecticide residues in soils / T.W. Fuhremann, E.P. Lichtenstein, and J. Katan --
Dieldrin removing from animal tissues / K.L. Davison --
Chlorine-mercury interactions in mercury derivatives of poly-chlorinated phenols and different chlorocarbons / Gary Wulfsberg, John Graves, June Griffiths, Don Essig, and R.J.C. Brown.
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I t may be hypothesized t h a t e i t h e r s u b s t r a t e quenching o f the e x c i t e d s t a t e by the dye may cause t h e decrease i n r e a c t i o n r a t e o r e l s e l i g h t i s r a t e l i m i t i n g a t c o n c e n t r a t i o n s higher than 6 χ 10" M. 6 5 Table I I Relativ Erythrosin Β Eosin Yellowish Rose Bengal Phloxin Β Fluorescein Rhodamine Β 12 10 10 5 1 0 Another q u e s t i o n o f c r i t i c a l importance t o t h i s study i s whether t h e dyes a r e d e t o x i f i e d d u r i n g t h e photodegradation process.
ACS Symposium Series; American Chemical Society: Washington, DC, 1978. DISPOSAL AND DECONTAMINATION OF PESTICIDES 46 : r -, Q 10 • „>»» Qβ Λ <) l2 • · 2 4 6 8 ROSE BENGAL (I0M) 6 \ • : \V » Figure 11. The apparent firstorder rate constant k plotted as a function of rose concentration t Figure 12. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1978. 4. ΗΕΓΓΖ AND WILSON Halogenated Xanthene Dyes Figure 13. W. Society: 20036 ACS Symposium Series;Washington, American Chemical Washington, DC, 1978.
3. KRANiCH ET AL. ΡOlychlorinated Hydrocarbons Figure 2. Product distribution version for hydrodechlorination vs. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1978. 27 28 DISPOSAL AND DECONTAMINATION OF PESTICIDES Aldrin-Dieldrin. The s t r u c t u r e s corresponding epoxide D i e l d r i n a r e : o f A l d r i n and i t s Dieldrin Aldrin E x p e r i m e n t a l d a t a o n r e l a t i v e mole f r a c t i o n o f h y d r o dechlorination product i n F i g u r e s 3 and 4.